Abstract

The cross-coupling reaction of allyltrifluorosilanes with aryl halides or aryl triflates promoted by a fluoride salt takes place at the α-carbon of the allyltrifluorosilanes in the presence of a catalytic amount of PdCl 2[Ph 2P(CH 2) n PPh 2] ( n = 2, 3), giving allylic arenes with high regioselectivity.

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