Abstract
With Cu(MeCN) 4BF 4 as catalyst and benzotrifluoride as solvent, the allylic oxidation of cyclohexene by tert-butyl perbenzoate was performed at room temperature in 75% yield without requiring an axcess of the olefin. The benzoyloxylation of other cycloalkenes in using such a substrate/perester ratio required additives such as DBU, DBN or DMAP, and often an increase of the reaction temperature.
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