Selective catalytic oxidation (SCO) of ammonia to nitrogen over Fe-exchanged zeolites prepared by sublimation of FeCl 3

Abstract

Fe-exchanged zeolites were prepared by subliming FeCl 3 and studied as catalysts for selective catalytic oxidation (SCO) of ammonia to nitrogen in the presence of oxygen. Fe-ZSM-5 prepared by sublimation of FeCl 3 at 700 °C showed excellent SCO performances at a very high space velocity (GHSV=2.3×10 5 h −1). Over 99% NH 3 conversion and nearly 100% N 2 selectivity were obtained at 400 °C. Among Fe-ZSM-5 catalysts prepared by subliming at different temperatures (denoted in parentheses, in °C), the catalytic performance decreased in the sequence of Fe-ZSM-5 (700) > Fe-ZSM-5 (600) > Fe-ZSM-5 (500), Fe-ZSM-5 (400), Fe-ZSM-5 (350). Among different Fe-zeolite catalysts prepared by subliming at 700 °C, the catalytic performance decreased in the sequence of Fe-ZSM-5 > Fe-MOR > Fe-FER > Fe-Beta > Fe-Y which are similar to the Fe-zeolites prepared by aqueous ion-exchange method. The activity for the SCR (selective catalytic reduction) of NO with ammonia was also investigated on different Fe-zeolites. The FT-IR results supported the two-step mechanism: NO is an intermediate for N 2 formation, NH 3 was first oxidized to NO by O 2, NO then reacts to the unreacted NH 3 to produce N 2.