Abstract
A novel mononuclear complex [LCuCl2(H2O)]CH2Cl2 (L = 2,6-bis(5-tert-butyl-1H-pyrazol-3-yl)pyridine) was synthesized and characterized by elemental analysis, ultraviolet visible (UV–Vis) spectrum, and fourier transform infrared spectroscopy (FTIR). The single-crystal X-ray diffraction structure analysis of the complex revealed that the copper atom was octahedrally coordinated. The catalytic potential of this complex was examined by the oxidation reaction of various aromatic substrates, such as styrene, ethyl benzene, α-methyl styrene, and benzyl alcohol. The oxidation reactions were carried out in acetonitrile with H2O2 and catalytic amounts of [LCuCl2(H2O)] at 70 °C. The catalyst exhibited good catalytic activity in the oxidation of benzyl alcohol (97.50% conv. in 1 h; TONs = 341.25), α-methyl styrene (97.72% conv. in 4 h; TONs = 342.02) and methyl styrene (99.00% conv. in 8 h; TONs = 346.50). The major products were 96.07% benzoic acid from benzyl alcohol, 93.54% acetophenone from α-methyl styrene and 86.38% benzaldehyde from styrene, respectively. A plausible catalytic mechanism involving an active cation [LCu2+] and an epoxy intermediate was proposed based the results of time-dependent electrospray ionization mass spectrometry (ESI-MS) of the reaction mixture.
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