Selective CH Borylation of Alkenes by Palladium Pincer Complex Catalyzed Oxidative Functionalization

Abstract

Die C-H-Borylierung einfacher Alkene gelang mit dem Palladium-Pinzettenkomplex 1 als Katalysator in Gegenwart von hypervalentem Iod und Bis(pinacolato)dibor(B2pin2)-Verbindungen. Die Borylierung verläuft vermutlich über eine Folge aus PdII→PdIV-Oxidation und Diboronat-Transmetallierung. TFA=Trifluoracetat Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.