Selective binding of Ni2+ and Cu2+ metal ions with naphthazarin esters isolated from Arnebia euchroma.

Abstract

Naphthazarin esters (C1-C4) isolated from the roots of Arnebia euchroma are found as skilled dual chemosensors for Ni2+ and Cu2+ among Pb2+ , Na2+ , K2+ , Hg2+ , Mg2+ , and Ca2+ metal ions. C1-C4 esters exhibited a red shift of 54 nm with Ni2+ and 30 nm with Cu2+ metal ions in absorption. There is a formation of red-shifted bands between 517 and 613 nm in the absorption spectrum of C1-C4 sensors on binding with Ni2+ and Cu2+ ions. The addition of Ni2+ and Cu2+ ions to sensors C1-C4 stimulates a remarkable color change from reddish pink to purple and light blue, respectively. These color changes can be identified with the naked eye. The significant downfield shifts of CO and OH peaks in nuclear magnetic resonance (NMR) spectrum confirm the chelation as binding mechanism. With ultraviolet-visble and NMR studies, it is found that C1-C4 esters possessed notable selectivity and sensitivity toward Ni2+ and Cu2+ over other metal ions.