Selective and Fast Detection of Fluoride-Contaminated Water Based on a Novel Salen-Co-MOF Chemosensor.

Abstract

The development of selective and fast optical sensitive chemosensors for the detection and recognition of different cations and anions in a domain is still a challenge in biological, industrial, and environmental fields. Herein, we report a novel approach for the detection and determination of fluoride ion (F–) sensing based on a salen-cobalt metal-organic framework (Co(II)-MOF). By a simple method, the Co(II)-MOF was synthesized and characterized using several tools to elucidate the structure and morphology. The photoluminescence (PL) spectrum of the Co(II)-MOF (100.0 nM/L) was examined versus different ionic species like F–, Br–, Cl–, I–, SO42–, and NO3– and some cationic species like Mg2+, Ca2+, Na+, and K+. In the case of F– ions, the PL intensity of the Co(II)-MOF was scientifically enhanced with a remarkable red shift. With the increase of F– concentration, the Co(II)-MOF PL emission spectrum was also professionally enhanced. The limit of detection (LOD) for the Co(II)-MOF chemosensor was 0.24 μg/L, while the limit of quantification (LOQ) was 0.72 μg/L. Moreover, a comparison of the Co(II)-MOF optical approach with other published reports was studied, and the mechanism of interaction was also investigated. Additionally, the applicability of the current Co(II)-MOF approach in different real water samples, such as tap water, drinking water, Nile River water, and wastewater, was extended. This easy-to-use future sensor provides reliable detection of F– in everyday applications for nonexpert users, especially in remote rural areas.