Abstract
Fe(II) complexes with pentadentate ligands, including N-heterocyclic carbene moieties, were prepared and electrostatically attached onto the perfluorinated surface of a mesoporous aluminosilicate. The heterogeneous catalysts were applied to the catalytic oxidation of cyclohexane and cyclohexene using H2O2 as an oxidant in CH3CN, demonstrating high performance and selectivity in alkane hydroxylation and cyclohexene epoxidation.
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