Abstract

AbstractNovel selective [3 + 2] cycloaddition reactions between in situ formed nonstabilized azomethine ylide generated from N‐benzyl‐1‐methoxy‐N‐((trimethylsilyl)methyl)methanamine enabled by Lewis acids and bioactive molecules isothiazol‐3(2H)‐ones have been developed. The reaction selectively afforded novel thiazolidines or cyclo‐fused oxazolidinones depending on Lewis acid catalyst system of reaction used.

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