Abstract

Crystal growth and segregation behavior in a confined, vertical melt zone in an InSb system were studied by allowing the upper and lower crystal‐melt interfaces to converge through controlled power reduction. Segregation inhomogeneities during the initial stages of solidification appeared exclusively in the upper crystal segment which grew under destabilizing thermal gradients. At decreased zone height, irregular dopant inhomogeneities, identical in appearance, were simultaneously formed in both the upper and lower crystal segments. With continuing solidification the irregular and random inhomogeneities became periodic (oscillatory) in nature. Periodic dopant striations of decreasing frequency were observed to the coalescence point of the two interfaces. The random and periodic segregation inhomogeneities, which formed simultaneously at the converging growth interfaces, were attributed to isostatic pressure effects which originate in the volume expansion of the confined solidifying melt.

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