Abstract

Abstract Literature data from several disciplines bearing on the shape of macromolecules in the amorphous bulk are reviewed in this report. Such diverse techniques as light scattering, SAXS and SANS, stress-optical determinations, and dielectric measurements combined with Monte Carlo modeling, all point to the possibility that the shape of the molecules is not exactly that of a Gaussian coil but is better described by the macromolecular domain model and is amenable to varying amounts of local order in the amorphous polymer bulk.

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