Abstract
The preparation and characterisation of organic molecular magnets is a non-trivial task which touches on many contemporary issues within chemistry.[...]
Highlights
The preparation and characterisation of organic molecular magnets is a non-trivial task which touches on many contemporary issues within chemistry
Amongst the more fashionable free radicals used in the design of magnetic materials are the persistent nitroxide and nitronyl nitroxide radicals, as well as verdazyl and thiazyl radicals
The formation of a stable radical itself does not infer any form of magnetically ordered phase
Summary
The preparation and characterisation of organic molecular magnets is a non-trivial task which touches on many contemporary issues within chemistry. As a number of authors have alluded to in their articles within this Special Issue, the design of organic ferromagnets merely requires ‘a stable organic radical with a three-dimensional network of ferromagnetic interactions’. A number of families of stable organic radicals have been identified which have proved to be suitable building blocks in the design of molecular materials.
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