Sedimentation and transformation of heavy metals during the transport from the Yellow River estuary to the sea: Evidence from surface sediments of the Yellow River subaqueous delta

Abstract

Estuarine and coastal areas are one of the ultimate sinks for terrestrial heavy metals which play a vital role on the aquatic ecosystem. This study examined heavy metals contents and speciations in Yellow River subaqueous delta surface sediment, to characterize their sedimentation and transformation during transport from estuary to the sea. The results showed that higher concentrations were found in the seaward and the shear front affected areas. The surface sediments were generally not contaminated by heavy metals, except for Cd was highly enriched, while the post-standardization spatial distribution reflected the effect of estuarine processes as a “filter” that effectively intercepting heavy metals. The dominated phase was residual fraction for Cr, Cu, Zn, Cd, while reducible fraction for Ni and carbonate fraction for Pb. The transformation of heavy metal species was mainly influenced by the changes in the sediment components such as carbonate minerals, organic matter and FeMn oxides.