Sedimentary polycyclic aromatic hydrocarbons (PAHs) along the mouth bar of the Yangtze River Estuary: Source, distribution, and potential toxicity

Abstract

The source, distribution, and potential toxicity of sedimentary polycyclic aromatic hydrocarbons (PAHs) along the mouth bar of the Yangtze River Estuary were investigated. Total concentrations of 17 PAHs in the study area ranged from 34.94 to 580.26 ng/g (mean value 146.31 ng/g). Results of PMF model revealed that mixed vehicle emissions (38.43%), natural gas combustion (24.98%), biomass combustion (20.76%) and coal combustion (15.83%) were sources of these sedimentary PAHs. The ERL/ERM, TEL/PEL and TEC/PEC values showed that the potential toxicity of PAHs was at low to medium level, but the presence of benzo[a]pyrene (BaP) and benzo[e]pyrene (BeP) requires more attention and research. Sedimentary PAHs pollution level in the three shoals (East Nanhui Shoal, Jiuduansha Shoal and Hengsha Shoal) was higher than that of the two passages (South Passage and North Passage), which demonstrates the possibility of restoration of the adjacent shoals by dredged soils in terms of PAHs pollution.