Abstract
Abstract The thermal gas-phase decompostion of methyl iodide was studied in He and Kr over the temperature range of 1025–1520 K and the total-density range of (0.96–2.3)×10−5 mol cm−3. The results showed that, at high temperatures, these inert gases act as “weak colliders.” From the low-pressure limit rate constants, the relative values of the collision efficiency, βc(M), were evaluted as; βc(He):βc(Ar):βc(Kr)=1.7:1.0:0.46 by connecting them with the previously reported data for an Ar mixture.
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