Secondary organic aerosol formation from xylenes and mixtures of toluene and xylenes in an atmospheric urban hydrocarbon mixture: Water and particle seed effects (II)

Abstract

Abstract Secondary organic aerosol (SOA) formation from the photooxidation of o-, p-xylene, and toluene with xylene mixtures was investigated in the UNC dual outdoor smog chambers. Experiments were performed with different initial background aerosol concentrations and levels of relative humidity (RH) in the environment of an eleven component mixture of non-SOA-forming dilute urban hydrocarbon mixture, oxides of nitrogen and sunlight. Post-nucleation was observed in most of the experiments in the 14–20 nm range except under the conditions with high background aerosol (>5 μg m−3) and with low o-xylene concentrations (