Second-order quadrupolar shifts as an NMR probe of fast molecular-scale dynamics in solids

Abstract

Molecular-scale dynamics on the nanosecond timescale or faster can have a measurable influence on isotropic NMR frequencies of quadrupolar nuclei. Although previously studied in solution, where it is usually referred to as the ‘dynamic shift’, this effect is less well known in solids. Here we demonstrate that multiple-quantum NMR measurements of isotropic quadrupolar shifts are a simple way to probe nanosecond timescale motions in solids. We measure the 11B (spin I = 3/2) shifts of the resolved boron sites in ortho-carborane as a function of temperature and interpret the results in terms of the known rapid tumbling dynamics.