Abstract
AbstractVery rapid, rapid, and slow second‐order reactions were studied in an isothermal turbulent flow reactor. The two aqueous reactant solutions were separately introduced through many alternate jets and the reaction took place in the resulting nonhomogeneous mixture. Very rapid reactions were diffusion controlled and were in agreement with earlier theory. All reactions followed second‐order rate laws based on time average quantities. The apparent reaction velocity constant was controlled by the mixing for very rapid reactions, by the chemical kinetics for slow reactions, and by both mechanisms for rapid reactions.
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