Abstract

An improved, second-generation aerosol shock tube (AST II) has been developed for the study of the chemical kinetics of low-vapor-pressure fuels. These improvements enable a wider range of fuel concentrations and enhanced spatial uniformity relative to our initial aerosol shock tube (AST I). In addition, the design of AST II limits the aerosol loading zone in the shock tube to a fixed region (1.2 m in length adjacent to the shock tube endwall). AST II achieves these improvements using a separate holding tank to prepare the aerosol mixture and a slightly under-pressure dump tank to carefully pull the aerosol mixture into the tube in a plug-flow. This filling method is capable of producing room temperature test gas mixtures of n-dodecane with equivalence ratios of up to 3.0 in 21 % O2, three times the loading achievable in the earlier AST I that used a flow-through strategy. Improvements in aerosol uniformity were quantified by measuring the liquid volume concentration at multiple locations in the shock tube. The measurements made over a length of 1.1 m of shock tube indicate that the AST II method of filling produces non-uniformities in liquid volume concentration of less than 2 %, whereas in the AST I method of filling the non-uniformities reached 16 %. The improved uniformity can also be seen in measurement of gas-phase fuel concentration behind the incident shock wave after the liquid droplets have evaporated. Significant reduction in the scatter of ignition delay times measured using AST II have also been achieved, confirming the importance of uniform loading of the aerosol in making high-quality combustion measurements.

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