Abstract
AbstractThe seco‐casbane framework, first isolated from Croton insularis, is surprisingly rare. Further evaluation of this Australian rainforest plant unearthed two additional members, EBC‐328 and EBC‐363. TD DFT predicted electronic circular dichroism (ECD) spectra were critical for remote absolute stereochemical determination. EBC‐328 displayed cytotoxic activity towards leukemia cells (K562). Potential biosynthetic relationships are discussed.
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