Abstract

Rivers as the link between terrestrial ecosystems and oceans have been demonstrated to transport a large amount of dissolved organic carbon (DOC) to downstream ecosystems. In the source region of the Yellow River (SRYR), climate warming has resulted in the rapid retreat of glaciers and permafrost, which has raised discussion on whether DOC production will increase significantly. Here, we present three-year data of DOC concentrations in river water and precipitation, explore the deposition and transport processes of DOC from SRYR. Results show that annual mean concentrations of riverine DOC ranged from 2.03 to 2.34 mg/L, with an average of 2.21 mg/L. Its seasonal variation is characterized by the highest concentration in spring and summer (2.65 mg/L and 2.62 mg/L, respectively), followed by autumn (1.95 mg/L), and the lowest in winter (1.44 mg/L), which is closely related to changes in river runoff under the influence of precipitation and temperature. The average concentration of DOC in precipitation (2.18 mg/L) is comparable with riverine DOC, while the value is inversely related to precipitation amount and is considered to be the result of precipitation dilution. DOC deposition flux in precipitation that is affected by both precipitation amount and DOC concentration roughly was 86,080, 105,804, and 73,072 tons/year from 2013 to 2015, respectively. DOC flux delivered by the river ranged from 24,629 to 37,539 tons/year and was dominated by river discharge. Although permafrost degradation in SRYR is increasing, DOC yield is not as significant as previously assumed and is much less than other large rivers in the world.

Highlights

  • Dissolved organic carbon (DOC) in surface water has crucial implications as a source of biological production [1,2]

  • Field samples were kept frozen in a refrigerator and transported to the State Key Laboratory of Cryospheric Science (SKLCS) of the Chinese Academy of Sciences (CAS) and Environmental Comprehensive Analysis Laboratory (ECAL) of Tianshui Normal University (TNU) until laboratory analysis

  • Flux (Fd ) of riverine DOC from source region of the Yellow River (SRYR) was calculated by daily DOC concentration (Cd ) multiplied by daily average discharge (Qd )

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Summary

Introduction

Dissolved organic carbon (DOC) in surface water has crucial implications as a source of biological production [1,2]. DOC levels change over time and space due to complex sources of catchments and aquatic ecosystems [12,13,14,15,16,17,18] Factors such as river discharge, basin precipitation, air temperature, the metabolism of phytoplankton, and atmospheric carbon dioxide concentration affect both the quality and quantity of DOC [12]. Annual runoff has decreased from the late 1980s to the 2000s owing to precipitation decline, and permafrost degradation has exerted more influence on surface runoff than glacier retreat [40] These processes may affect soil/rock erosion and solute release [41]. This paper primarily focused on the seasonal and annual variations of DOC concentrations, fluxes, and yields estimation in SRYR, the potential influence of hydrological and meteorological factors, as well as a comparison with other watersheds around the world

Study Area
Sample Collection
Laboratory Analysis
Flux Calculation and Statistical Analysis
Seasonal Variations in DOC Concentrations in the River
DOC Fluxes in the River
DOC Concentrations and Fluxes in Precipitation
DOC and Inorganic Ions
Conclusions
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