Seasonal variation of dissolved Cs-137 concentrations in headwater catchments in Yamakiya district, Fukushima Prefecture

Abstract

<p>The Fukushima Daiichi Nuclear Power Plant (FDNPP) accident occurred on March 11, 2011, and a large amount of Cs-137 was released into the environment. It is important to clarify the behavior of radioactive cesium-137 in headwater catchments because most of the Cs-137 falls and is deposited in forest areas and is transported in the environment through river systems.</p><p>The purpose of this study was to clarify the influence of water quality composition and organic matter on the seasonal variation of dissolved Cs-137 concentrations in stream water based on long-term monitoring since 2011 at four headwaters catchments in Yamakiya district, Fukushima Prefecture (Iboishiyama, Ishidairayama, Koutaishiyama, Setohachiyama), located about 35 km northwest of FDNPP.</p><p>Water temperature, pH, and EC were measured in the field, and SS and coarse organic matter were collected using a time-integrated SS (suspended sediments) sampler and organic matter net. The Cs-137 concentrations was measured in the laboratory using a germanium detector. Concentrations of cations (Na⁺,K⁺,Ca²⁺,Mg²⁺,NH₄⁺) and anions (Cl⁻,SO₄²⁻,NO₃⁻,NO₂⁻,PO₄²⁻) were measured by ion chromatography after 0.45μm filtration. In addition, dissolved organic carbon (DOC) concentrations was measured using a total organic carbon analyzer.</p><p>The results showed that K⁺, which is highly competitive with Cs-137, was detected at Iboisiyama, Ishidairayama, and Koutaishiyama, while NH₄⁺ was only detected in some samples at Iboishiyama. There was no obvious relationship between dissolved ion concentration and water temperature, and between dissolved ion concentration and dissolved ¹³⁷Cs concentration at all sites. However, a positive correlation between dissolved cesium concentration and water temperature and DOC and water temperature was observed at all sites regardless of the presence of K⁺ and NH₄⁺. On the other hand, there was no clear relationship between the cesium concentrations in SS and organic matter and water temperature. These results suggest that the seasonal variation in dissolved Cs-137 concentrations in stream water with water temperature could be caused by the seasonality of microbial decomposition of organic matter.</p>