Seasonal variability in multimedia transport and fate of benzo[a]pyrene (BaP) affected by climatic factors

Abstract

The impact of meteorological factors on the transport behavior and distribution of volatile and semi-volatile organic pollutants has become an area of increasing concern. Here, we analyzed seasonal variation in climatic variables including wind, temperature, and precipitation to quantitatively assess the impact of these factors on the multimedia transport and fate of BaP in the continental region of China using a Berkeley-Trent (BETR) model. The advective rates of air exhibited an increasing trend of autumn (1.830 mol/h) < summer (1.975 mol/h) < winter (2.053 mol/h) < spring (2.405 mol/h) in association with increasing wind speed, indicating that lower atmospheric BaP concentrations are present in regions with high wind speeds and advective rates. The air-soil transport rates (0.08–45.55 mol/h) in winter were higher than in summer (0.07–32.41 mol/h), while low winter temperatures accelerate BaP accumulation in terrestrial ecosystems due to cold deposition. Cold deposition effects were more evident in northern regions than in southern regions. Further, increasing precipitation enhanced air-soil and soil-freshwater transport rates with the correlation coefficients of r = 0.445 and r = 0.598 respectively, while decreasing the air-vegetation transport rates (r = 0.475), thereby contributing to the accumulation of BaP in soils and freshwaters. In the light of the potential dispersion of BaP pollution at regional and global scales affected by these key climatic factors, this indirectly indicated the impact of future climate change on the BaP transport. Thus, flexible policy interventions should be enacted to slow future climate change.