Seasonal fluxes of major ions to a high altitude cold alpine glacier

Abstract

A 13 m fimcore was recovered in April 1991 at Col du Dome (4250 m.a.s.l.), located below the Mont Blanc summit (Northern French Alps). The core spans a complete sequence of 3.5 years of high alpine precipitation, as indicated by the stratigraphic and the isotopic profiles. Subsamples were analysed for Na +, NH 4 +, K +, Mg 2+, Ca 2+, Cl −, NO 3 − and SO 4 2− using ion chromatography, and for H + or HCO 3 − using a titration technique. In absence of alkaline Saharan dust, the snow is slightly acid (2–20 μ Eq l −1. All analysed ions show a sharply pronounced seasonal pattern, with concentrations, extremely low in winter, increasing in spring and reaching a maximum in summer. This picture supports the idea that in winter the high alpine sites are generally not affected by polluted air masses from lower altitudes, whereas during spring and summer, vertical convective transport significantly affects the highest sites located well above 4000 m a.s.l. The lowest impurity levels of alpine winter snow are comparable with central Greenland values, suggesting that at this time, and just in opposite to what occurs in the Arctic, the highest alpine regions are representative of the continental free troposphere. Annual and seasonal deposition fluxes are calculated. In order to assess the spatial representativeness of these results, a comparison is made with similar records obtained from a 10m firncore recovered in summer 1991, at the low accumulation site Colle Gnifetti (4450 m.a.s.l.) located in the Swiss Alps, 80 km east of Col du Dôme. An excellent agreement is found between the overall mean isotopic and chemical composition of the two firncores, suggesting that, since clean winter snow is well preserved at Col du Dome, this site is presumably more influenced by precipitation during summer. Finally, the attractive perspectives for deep drilling in the Mont Blanc area are assessed, and the merits of making use of both sites, where comparable and complementary information can be obtained, are outlined.