Abstract

We measure by time of flight the energy distribution of positronium (Ps) emitted normally to a clean Al(111) surface that is bombarded with energetic (1.5--4.5 keV) positron pulses. The data are consistent with the predictions of a free-electron model for nonadiabatic Ps emission with less than ${10}^{\mathrm{\ensuremath{-}}3}$ of the Ps emitted normal to the surface in a monoenergetic peak at the maximum allowable energy. The Ps work function at 300 K is (-2.536\ifmmode\pm\else\textpm\fi{}0.035) eV in agreement with the (-2.519\ifmmode\pm\else\textpm\fi{}0.027) eV obtained from the sum of the electron and positron work functions minus the binding energy of Ps.

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