Abstract

Near-surface voids on a cement concrete sample were successfully sealed by applying a metal-ethylenediaminetetraacetic (EDTA) acid complex solution, followed by treatment with high-heat hydrogen/oxygen (H2-O2) coupled flame. The calcium aluminates used for sealing were fabricated on cement substrates using calcium-aluminate (Ca,Al)-EDTA solutions prepared at various elemental ratios. The sealing effects were investigated through crystal & pore structure analysis and water permeability tests, using X-ray computed tomography (X-CT). Existence of the calcium aluminates were confirmed. From X-CT analysis, the average void diameter was changed from 16 μm to 10 μm with the calcium aluminate’s sealing. A sealing process model combining metal-EDTA complex solutions and high-heat treatment, intended for the surface sealing of cement concretes used in construction, was comprehensively proposed.

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