Abstract
Not the binary compound tetraselenium dinitride, as previously reported, but rather Se3N2Cl2 (1) is the product of the reaction of trimethylsilyl azide and selenium monochloride in dichloromethane [Eq. (a)]. Compound 1 can also be obtained quantitatively in a pure form from selenide 2 and selenium tetrachloride/selenium monochloride [Eq. (b)], and is of interest as a synthetic building block in the little developed SeN chemistry. equation image equation image
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