Abstract

Ameliorative effects of sheep slaughterhouse waste-derived soil amendments (struvite, blood meal, bone meal) were explored and quantified by a series of comparative greenhouse trials. A scoring matrix system was developed for 25 different test plants using 300 agricultural measurements obtained for three basic growth parameters (fresh-dry plant weights and plant heights) and four different fertilizer sources including solid vermicompost. More than 70% of NH4+-N recovery from sheep slaughterhouse wastewater was achieved using a chemical combination of MgCl2.6H2O+NaH2PO4.2H2O, a molar ratio of Mg2+:NH4+-N:PO43-P=1.2:1:1, a reaction pH of 9.0, an initial NH4+-N concentration of 240mg/L, and a reaction time of 15min. According to SEM micrographs, surface morphology of struvite exhibited a highly porous structure composed of irregularly shaped crystals of various sizes (11.34-79.38μm). FTIR spectroscopy verified the active functional groups on the proximity of all fertilizer sources within the spectral range of 500-3900cm-1. TGA-DTG-DSC thermograms of struvite revealed that the mass loss occurred in two temperature regions and reached a maximum mass loss rate of 1.63%/min at 317°C. The average percentages of increase (57.55-100.62%) and performance points (69-79) corroborated that the fertility value of struvite ranked first on average in cultivation of the analyzed plant species. Findings of this agro-valorization study confirmed that sheep slaughterhouse waste-derived fertilizers could be a beneficial way to promote bio-waste management and environmentally friendly agriculture.

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