Screen-printed Organic Electrochemical Transistors for the detection of ascorbic acid in food

Abstract

Methods traditionally used for ascorbic acid (AA) detection in food are often expensive and complex, making them unsuitable for day-to-day determinations. In this work, we report on the use of all-PEDOT:PSS Organic Electrochemical Transistors (OECTs) for fast, simple and low-cost determination of AA in food. The performance of these OECTs was tested first with in lab-prepared solutions of AA with different concentrations. The effect of the geometry on the transistors performance for AA sensing was also investigated by comparing the response of two OECTs with different channel and gate areas ratio (γ), in terms of current modulation, sensitivity, background signal and limit of detection (LOD). OECTs with smaller gate electrode than the channel (large γ) show the best performance for AA sensing: these devices display smaller background signal, higher sensitivity, larger modulation and better LOD value (80 μM). Since the AA content in food rich in Vitamin C is in the mM range, these transistors can be considered sensitive enough for quantitatively monitoring AA in food. In order to demonstrate the reliability of the proposed sensors in real food samples, the response of these transistors was additionally measured in a commercial orange juice. The amount of AA obtained with the OECTs is in good agreement with that determined by HPLC and with values reported in the literature for orange juices. Furthermore, these OECTs can be considered promising candidates for the selective detection of AA in the presence of other interfering antioxidants.