Abstract
Abstract The multi-state semiclassical method proposed by Sharp and Rapp for calculating the vibrational transition probabilities of harmonic oscillators in collision was extended to Morse oscillators. Model calculations have been carried out for the excitation of a vibrational ground-state hydrogen molecule colliding with a helium atom at varying relative velocity. It has been shown that the Morse oscillator model gives greater transition probabilities than the corresponding harmonic oscillator model.
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