SCIENTIFICLY BASED CALCULATION METHODS AND EXPERIMENTAL DATA BASES FOR THE PREVENTION OF PREMIUM FIRE EXPLOSIONS AND UNSAFE EXPLOSIONS OF PYROTECHNIC MULTICOMPONENT NITRATE-METALLIZED MIXTURES UNDER EXTERNAL THERMAL

Abstract

Problem statement. Methods of preventing the occurrence of forced fire-hazardous destruction of products in the event of exposure to external thermal actions are of great practical importance. At the same time, they should be based on scientifically based methods for determining the critical values of parameters of thermal effects on products and technological parameters of mixture charges, the excess of which leads to premature fire-hazardous destruction of products. To develop such methods, it is necessary to have the results of theoretical and experimental studies of the processes of heating the shells of mixture charges for various external heat flows and their thermoreaction times, as well as the processes of ignition and development of their combustion under different external conditions. Purpose of the article. To form the results of theoretical studies in the form of scientifically based methods that allow preventing and controlling the premature ignition of mixture charges, the explosive development of their combustion process and the fire-hazardous destruction of products under conditions of external thermal effects, as well as the compilation of the results of experimental studies into a single database with determination of the influence of the technological parameters of the mixtures on the characteristics of their ignition processes and the development of combustion, the use of which allows reducing the number of fire-explosive destruction of products in conditions of elevated heating temperatures and external pressures. Conclusion. Scientifically based methods of determining the critical values of the parameters of external thermal actions for the quantitative assessment of the level of fire safety of pyrotechnic products based on multi-component nitrate-metallized mixtures have been developed. A scientific and technical base of experimental data was created to determine the regularities of the influence of a wide class of technological parameters of mixtures on the main characteristics of the processes of ignition and development of combustion of mixtures (ignition temperature, induction time, speed of combustion development) under conditions of external thermal actions (elevated heating temperatures, external pressures, etc.), which makes it possible to determine the probability of fires occurring at facilities where products are stored.