Abstract

We present the science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems, targeting an evolution in technology, that might lead to impacts and benefits reaching into most areas of society. This roadmap was developed within the framework of the European Graphene Flagship and outlines the main targets and research areas as best understood at the start of this ambitious project. We provide an overview of the key aspects of graphene and related materials (GRMs), ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries. We also define an extensive list of acronyms in an effort to standardize the nomenclature in this emerging field.

Highlights

  • Tailoring electronic and optical properties in graphene can be achieved by lateral confinement of its 2d electron gas from the mesoscopic regime down to the molecular scale,[289,290,291,292,293,294,295] The dominant approach consists in using inorganic resist to lithographically define graphene nanoribbons (GNRs),[296,110,297,298] A resist-free approach can be achieved by focused ion beam lithography,[299,300] the transport in ion-etched GNRs is strongly dominated by edge disorder and amorphization[299,300,301,302] which calls for alternative approaches

  • In the case of solvent stabilisation, good solvents are those with surface energy matching that of the exfoliated materials.[38]. This results in the enthalpy of mixing being very small.38,1052. Because these exfoliation methods are based on VdWs interactions between the flakes and either the solvent molecules or surfactant tail group, stabilisation does not result in any significant perturbation of the flake properties

  • graphene ring oscillators (GROs) and inverters could find applications in digital circuits operating at extremely high frequency (EHF; f > 100 GHz) in which high operating speed could be traded off against power dissipation, reduced voltage swing, and circuit complexity1170,1172,1173,1216 These ultra-high speed digital circuits were developed to perform data conversion at the transmitting/ receiving side of serial EHF lines,1217 such that information carried by EHF digital signals can be processed at lower clock rates by low-power, highly integrated, and parallel Si Complementary metal oxide semiconductor (CMOS) logic

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Summary

Introduction

New technologies and materials: towards a novel technological platform.

Fundamental research
Production
Electronic devices
Spintronics
Photonics and optoelectronics
Sensors
Flexible electronics
12. Biomedical applications
13. Conclusions
Graphene-based disruptive technologies: overview
Scientific output
Electronic transport
Spectroscopic characterization
Magnetism and spin transport
Polycrystalline graphene
Thermal and mechanical properties of graphene
Artificial graphene structures in condensed-matter systems
Atomic scale technology in graphene and patterned graphene
Hybrids of graphene and other 2d crystals
2.10. Multiscale modelling of graphene-based structures and new 2d crystals
2.11. Graphene for high-end instrumentation
In vitro impact
Cytotoxicity effects on graphene-coated surfaces
Biodegradation
Environmental impact
Perspective
Method Micromechanical cleavage
Graphene production
Growth on SiC
Growth on metals by precipitation
Chemical vapour deposition
Molecular beam epitaxy growth of graphene on insulating surfaces
Atomic layer epitaxy
Heat-driven conversion of amorphous carbon and other carbon sources
Chemical synthesis
Nano-ribbons and quantum dots
4.10. Transfer and placement
4.11. Contamination and cleaning
4.11.1. Cleaning of graphene produced by MC
4.12. Inorganic layered compounds
4.13. Graphene and other 2d crystal hybrids
Opening a band-gap in graphene
High frequency electronics
Layered materials-based devices
Novel vertical and planar transistors and devices
Graphene spintronics
Spin injection in graphene
Graphene spintronic devices for sensing
Graphene spin gating
Graphene qubits
Spintronics using other 2d crystals and heterostructures
Theory and quantum simulation
Outlook
Graphene saturable absorbers and related devices
Graphene plasmonics
Graphene-based antennas
Hybrid graphene-nanocrystal for light emitting devices
Graphene-based nanoscale optical routing and switching networks
Contact sensors
Non-contact sensors
Key technology enablers
Innovative flexible devices and user interfaces for consumer electronics
10.1. Batteries
10.2. Supercapacitors
10.4. Graphene solar cells
10.5. Thermoelectric devices
10.6. Nanogenerators
11.1. Polymer-based composites
11.2. Ceramic-based composites
11.4. Photonic polymer composites
12.1. Imaging and diagnosis
12.2. Hyperthermia: photothermal ablation of tumours
12.3. Targeted drug delivery
12.4. Gene transfection
12.5. Bioelectronics and biosensors
Findings
12.7. Single-molecule genomic screening devices

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