Abstract

Zusammenfassung The infrared spectra of gaseous HSiCl 3 ahd DSiCl 3 down to 140 cm −1 are reported. A force field reproduced by Table 6 has been computed using frequencies, 35 Cl/ 37 Cl isotope splittings and ζ constants from band contours. f SiCl is calculated to be 2·918, f SiCl/SiCl, being 0·068 mdyn/A.

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