Schwefel-stickstoff-verbindungen VII. Darstellung und reaktionen einiger perfluoraromatischer schwefel-stickstoff-verbindungen

Abstract

Some reactions of the derivatives of pentafluorobenzenesulfenic, -sulfinic, and -sulfonic acid are described. By the reaction with thionyl chloride N-sulfinylpentafluorobenzenesulfenamide and -sulfonamide were prepared. N-sulfinylpentafluorobenzenesulfenamide was also prepared by the reaction of pentafluorobenzenesulfenyl chloride with N-sulfinyltrimethylsilylamine. Furthermore the reaction of bis(pentafluorophenylthio)amine with thionyl chloride and the reactions of pentafluorobenzenesulfenamide with sulfur dichloride and sulfur tetrafluoride were investigated.