Schiff base derivative flame-retardant endowing epoxy resin with toughness, transparency, and high flame retardancy

Abstract

In this study, a novel phosphorus-containing flame retardant, SMAE, was prepared through a nucleophilic addition of N,N'-bis(salicylidene)ethylenediamine (SAED) and phenyl hypophosphite. SMAE can dissolve well in epoxy resin and provides molecular-level flame retardancy. By using SMAE as a co-curing agent and DDM to cure epoxy resin, EP/SMAE composites with excellent flame retardancy and good mechanical properties were obtained. As the dosage gradually increases, the limited oxygen index (LOI) values continue to rise. At a 5 % dosage, the Limiting Oxygen Index (LOI) value can reach 39.7 % and meet the UL 94 V-0 standard. It is observed that SMAE mainly exerts a blowing-out effect in EP. In addition, the use of SMAE as a co-curing agent can improve the impact strength of EP. The impact strength of 5 % SMAE/EP can reach 14.15 kJ/m2, which is 25 % higher than that of pure EP.