Abstract
Fourteen new addition complexes of the type R 2SnCl 2 · 2 HOC 6H 4CHNR′ have been synthesized by the reactions of diorganotin dichlorides, R 2SnCl 2 (where R = Me, Et, n-Bu and Ph), with N-alkyl(aryl)salicylideneimines, HOC 6H 4CHNR′ (where R′ = Me, Et, n-Bu and Ph), in non-aqueous solvents. The complexes are non-electrolytes in nitrobenzene. Infrared and Mössbauer spectroscopic studies indicate an all- trans octahedral geometry for the complexes.
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