Scavenging of copper(II) ions, phosphate(V) ions, and diuron from aqueous media by goethite modified with chitosan or poly(acrylic acid)

Abstract

Goethite was modified by chitosan (CS) or poly(acrylic acid) (PAA) to improve its adsorptive abilities toward components of agrochemicals, i.e., copper ions (Cu), phosphate ions (P), and diuron. The pristine goethite effectively bound Cu (7.68 mg/g, 63.71%) and P (6.31 mg/g, 50.46%) only in their mixed systems. In the one adsorbate solutions, the adsorption levels accounted for 3.82 mg/g (30.57%) for Cu, 3.22 mg/g (25.74%) for P, and 0.15 mg/g (12.15%) for diuron. Goethite modification with CS or PAA did not yield spectacular results in adsorption. The maximum increase in adsorbed amount was noted for Cu ions (8.28%) after PAA modification as well as for P (6.02%) and diuron (24.04%) after CS modification. Both goethite modifications contributed to clear reduction in desorption of pollutants (even by 20.26% for Cu after PAA coating), which was mainly dictated by electrostatic attractive forces and hydrogen bonds formation occurring between macromolecules and impurities. The only exception in this phenomenon was Cu desorption from CS-modified solid—the polymer made it higher (to 95.00%). The Cu adsorption on PAA-modified goethite enhanced solid aggregation and thus facilitated metal cation separation from aqueous media. Consequently, the goethite modification with PAA was considered more promising for environmental remediation.