Scattered light and accuracy of the cross‐section measurements of weak absorptions: Gas and liquid phase UV absorption cross sections of CH3CFCl2

Abstract

Ultraviolet absorption cross sections of CH3CFCl2 (HCFC‐141b) were determined in the gas phase (190–260 nm) and liquid phase (230–260 mm) at 298 K. The liquid phase absorption cross sections were then converted into accurate gas phase values using a previously described procedure. It has been demonstrated that scattered light from the shorter‐wavelength region (as little as several parts per thousand) can seriously compromise the absorption cross‐section measurement, particularly at longer wavelengths where cross sections are low, and can be a source of discrepancies in the cross sections of weakly absorbing halocarbons reported in the literature. A modeling procedure was developed to assess the effect of scattered light on the measured absorption cross section in our experiments, thereby permitting appropriate corrections to be made on the experimental values. Modeled and experimental results were found to be in good agreement. Experimental results from this study were compared with other available determinations and provide accurate input for calculating the atmospheric lifetime of HCFC‐141b.