Abstract

Martensite (α’) usually plays an important role in the hydrogen embrittlement (HE) of metastable austenitic stainless steels (γ-SS). However, there is still controversy about the location of hydrogen accumulation after martensitic transformation in γ-SS. Scanning Kelvin probe force microscopy (SKPFM) combined with finite element analysis (FEA) have been used to study the hydrogen distribution and evolution in hydrogen-precharged γ-SS after martensitic transformation. It is found that hydrogen accumulates in austenite (γ) adjacent to α′ after the formation of α′. The peak of hydrogen concentration in γ induced by α′ increases first and then decreases as hydrogen diffuses further into γ.

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