Abstract
In the title compound, C8H11N2S+·C12H10NO3S−, the NH group of the S-benzylthiuronium is protonated and the interplanar angle between the phenyl ring and the CH2—S=C(NH2)2 unit is 47.44 (10)°. In the 4-anilinobenzenesulfonate anion, the interplanar angle between the two rings is 44.07 (8)°. In the crystal structure, anions are linked into chains along the c-axis direction by N—H⋯O hydrogen bonds, while additional N—H⋯O interactions link the cations to the anions in chains along the b-axis direction. These chains are further interconnected into a two-dimensional network parallel to the bc plane by C—H⋯O interactions. C—H⋯π contacts are also observed.
Highlights
In the title compound, C8H11N2S+C12H10NO3S, the NH group of the S-benzylthiuronium is protonated and the interplanar angle between the phenyl ring and the CH2—
Anions are linked into chains along the c-axis direction by N—H O hydrogen bonds, while additional N—H O interactions link the cations to the anions in chains along the b-axis direction
These chains are further interconnected into a two-dimensional network parallel to the bc plane by C—H O
Summary
USM, Penang, Malaysia, bCrystal Materials Research Unit, Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla 90112, Thailand, c. C8H11N2S+C12H10NO3S, the NH group of the S-benzylthiuronium is protonated and the interplanar angle between the phenyl ring and the CH2—. Anions are linked into chains along the c-axis direction by N—H O hydrogen bonds, while additional N—H O interactions link the cations to the anions in chains along the b-axis direction. These chains are further interconnected into a two-dimensional network parallel to the bc plane by C—H O interactions.
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