Abstract
This article discusses the results of comprehensive studies of Sb-As ores of the Lojan deposit, located in the north-east of the Republic of North Macedonia (RSM), near the border with Serbia. 5 types of Sb-As ores have been identified: breccated realgar-auripigment ores, realgar breccias, breccated antimonite ores, massive, almost monomineral realgar ores, as well as realgar-antimonite nest-shaped ores. The ores are characterized not only by an unusual paragenesis of nickel, arsenic and antimony minerals, but also by a very close fusion of antimonite, realgar and collomorphic quartz. A wide range of elements in ores (As, Sb, Cr, Ti, Mn, Ni, Mo, Co, Ag, Tl, U, etc.) is apparently due to the combination of mineralization in ores of several different-time parageneses. As a result of thermometric studies of fluid inclusions in quartz, Thom vary from 180 OC to 220 OC (the average value is 201 OC). Studies of the isotopic composition of sulfur in antimonite and realgar have shown rather narrow ranges of δ34S values from -5.19 to -0.26 and from -4.80 to 1.92, respectively, which indicates an endogenous source of sulfur. The results obtained allow us to attribute the Lojan deposit to the epithermal class
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