Abstract
Semi-crystalline high density polyethylene (HDPE) samples were irradiated with 1.157GeV 56Fe ion beams to fluences ranging from 1×1011 to 6×1012ions/cm2. The radiation induced changes in nano/microstructure were investigated with small angle X-ray scattering (SAXS) technique. The scattering contributions from HDPE matrix and ion tracks are successfully separated and analyzed through tilted SAXS measurements with respect to the X-ray beam direction. Lorentz correction, one-dimensional correlation function calculation, fractal nature analysis of the isotropic scattering pattern reveal that HDPE long period polymeric structures are damaged and new materials, possibly clusters of carbon-rich materials, are formed inside the ion tracks. Least square curve fitting of the scattering contribution from the ion track reveals that the track is composed of a core of about 5.3nm in radius, characterized by a significant density deficit compared to the virgin HDPE, surrounded by a shell of about 4.3nm in thickness with less density reduction.
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