Sandcastle worm-inspired phytic acid and magnesium oxychloride cement copolymerization for performance enhancement

Abstract

The development of magnesium oxychloride cement (MOC) can convert wastes in the potash industry into valuable products and reduce CO2 emission. The use of acid radicals has the potential to enhance the water resistance of MOC. However, because of the internal stress formed during the crystallization process, the occurrence of cracks accompanied by a significant decrease in the mechanical properties is inevitable. Inspired by the sandcastle worm and organic-inorganic copolymerization, a novel strategy was proposed, which employed phytic acid (PA) to copolymerize with phase 5 crystals to reduce the internal stress and prevent crack generation. XPS and TG-DSC analyses revealed that organic-inorganic copolymers were successfully produced. Furthermore, the compressive strength (CS) and water resistance of MOC-PA were significantly enhanced. The enhanced properties were associated with the coordination bonds and high tension of the rigid rings in phytic acid, which was sufficient to overcome the internal stress. Additionally, the repeated hydrolysis of rod-like phase 5 generated a gel-like phase from the outside inward, enhancing their water resistance. Compared with MOC-0, MOC-0.6 showed a 17.8% increase in CS and a 102.3% increase in water resistance. The microscopic mechanisms of the enhanced CS and water resistance of high-performance greener cements were proposed.