Samarium(II) iodide

Abstract

This article has no abstract. Keywords: reductions with SmI2; alkylation of aldehydes; reductive cleavage of isoxazoles; α-diketones; selective reduction; α-hydroxy ketones; barbier cyclization; hydroxymethylation of carbonyl compounds; pinacol coupling; intramolecular barbier-type cyclization; reduction of α-alkoxy ketones; reduction of α,β-epoxy ketones; chiral aldols; coupling of allylic acetates with ketones; homoallylic alcohols; oppenauer oxidations; coupling of carbonyl compounds with alkenes; intramolecular pinacol reduction; allenic alcohols; barbier-type cyclization of α-(ω-iodoalkyl)-β-keto esters or amides; asymmetric intramolecular reformatsky reactions; bicyclic γ-lactones; reduction of α,β-epoxy esters to β-hydroxy esters; reduction of vinyloxiranes; dihydrofurans; γ-lactones; medium-ring lactones; HMPT catalysis; cleavage of β-chlorotetrahydrofurans; reductive cyclization; cyclopropanols; decarbonylation of α-alkoxy acid chlorides; α,β-enones; pinacol coupling of dialdehydes; reductive coupling of imines; anti-1,3-diol monoesters; pyranose cyclopentanes; coupling of ketones with alkenes; reductive cyclization of carbonyls with an alkyne group; R1R2CO R1CH(CN)R2; deoxygenation of α-alkoxy(hydroxy) esters; alkene synthesis; aryl radical cyclization; α,α′-dihydroxy ketones; vic-diketones; review; coupling of lactones and ketones; reduction of ArCOOH and derivatives; aryl radical cyclization; barbier/aldol reactions of enones; α-ketols; addition of ClCH2OCH2C6H5 to ; cyclization of alkynyl halides; methylenecyclopentanes; intramolecular reformatsky reaction; reductive cyclization of unsaturated ketones; vinylogous barbier reaction; reduction of RNO2; review of SmI2 reduction of halides and radicals; preparation; reductions; reaction of organochalcogenides; organosamarium reactions with carbonyl compounds; three-component coupling; reductive enolization; carbonyl couplings; eliminations; carbon radical generation; cyclopropane fission; other reactions; barbier reactions; condensation of α-haloketones; reformatsky reactions; C-glycosides; 2,3-pentadiene-1,5-diols; reduction of N–X bonds; cleavage of three-membered heterocycles; pyrrolidines; cleavage of S–C bonds; reductive couplings; γ-hydroxy amides; Ene reactions; 1-Aza-1,3-dienes; expansion of cyclobutanones; tetrahydrofurans; reductive alkylation; cyclic 1,2-amino alcohols; reductions; defunctionalization; α-functionalized organosamariums; halide-carbonyl reactions; reaction of ketyls; cross-coupling reactions; conjugate additions; rearrangements; reductions; reductive couplings; aldol and reformatsky reactions; δ-lactones; barbier reactions; reaction of ketyls; cyclizations; eliminations and cycloadditions; reagent preparation; elimination reactions; reduction; coupling; alkylation; condensation + reduction; additions and cycloadditions; ring expansion and cleavage; reagent preparation; reduction; coupling reactions; condensation; addition reactions; rearrangement-reduction; acyl radical transfer; Sm dienolates; elimination; reductive addition; reductive cleavage; condensations; reduction; ring formation; alcoholysis; addition to CO; elimination; reduction—addition; reduction; reactions; reductive cleavage; coupling reactions; cyclization; hydroamination; samarium(III) chloride; Negishi coupling; samarium(III) tris(hexamethyldisilazide); Wolff rearrangement; silver trifluoroacetate