Abstract
AbstractFor the cryoscopic investigation of salt‐like materials it is of great advantage to use, as solvents, melts of salts, transitition points of salt hydrates or eutectic mixtures. An apparatus is described allowing such measurements to be carried out with small amounts of substance of the order of 10−3 formula weights. Data are given for NaCl, NaOH, ZnSO4, Na2CdY, Na2CoY, [Ag2(en)2]SO4 («en» = ethylendiamine; Y4− = anion of EDTA), using Na2SO4, 10H2O as solvent. The ethylenediamine‐silver complex is shown to contain the binuclear cation [Ag2(en)2]2+, in agreement with the result of equilibria measurements carried out earlier.
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