Abstract

Abstract The reactivity and the stability of organomanganese reagents prepared from the ate complexes MnX 2·2LiBr (X= Br,I) and MnCl 2·R 4NX (X= Br, Cl) were studied. The preparation and the use for synthetic applications of stable sec- and tert-alkylmanganese bromides in ether as well as the acylation of RMnCl by R'COOCOOEt in THF were successfully achieved for the first time.

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