Abstract
Chiral aldehydes and ketones, derivatives of proline and piperidine-2-carboxylic acid have been synthesized and their Schiff bases with glycine form copper complexes which were hydroxyethylated with acetaldehyde; decomposition of the complexes obtained gave threonine with an optical purity of up to 97–100% and with threo/allo ratios of up to 19 : 1, and the chiral reagents can be recovered and reused with no loss of optical purity of the threonine.
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