Abstract
The cation of the title compound, [Ir(C10H15)(C4H8NO2S)](CF3SO3)·0.5H2O, contains a half-sandwich [Ir(C5Me5)]2+ fragment, the IrIII atom of which is coordinated by the tridentate S-methylcysteinate ligand (S-MecysO) in a κ3N,O,S manner. An RIr configuration is observed for the transition metal and an SS configuration for the chiral thioether S atom.
Published Version
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