S-HGMS coupling with alkali precipitation for the scale inhibition in recirculating cooling water with high hardness: Performance, mechanism and field application

Abstract

Recirculating cooling water (RCW) contains various scale-forming ions, such as Ca2+ and Mg2+, which tend to form the hard scale in the heat transfer process. In this study, a novel method via superconducting high-gradient magnetic separation (S-HGMS) coupling with alkali precipitation for scale inhibition in RCW was proposed, which could achieve efficient removal of total hardness (91.64 %). The scale inhibition mechanism of the S-HGMS coupling is attributed to the increase of ionic hydration shell thickness and the formation of hydrogen bonds, enhancing the solubility of scale-forming ions and diminishing their nucleation rate. Furthermore, this coupling induces a crystalline transformation from recalcitrant calcite to looser aragonite, contributing to the separation of scale from the pipe wall. Significantly, the proposed method was implemented in the field application by establishing a pilot-scale system with a capacity of 800–1000 L/h, which realized a stable reduction in the total hardness of the RCW from 1270 mg/L to below 127 mg/L at a magnetic flow ratio of 0.05 T·s/m. Moreover, the heat exchanger surface scaling was effectively controlled after 71 days of continuous treatment. This study helps promote the industrial application of S-HGMS technology for scale inhibition in high-hardness water.