Ruthenium(IV) porphyrin catalyzed highly selective oxidation of internal alkenes into ketones with Cl2pyNO as terminal oxidant

Zhi-Ming Wang,Xue-Ling Sang,Chi-Ming Che,Jian Chen

doi:10.1016/j.tetlet.2014.01.098

Ruthenium(IV) porphyrin catalyzed highly selective oxidation of internal alkenes into ketones with Cl2pyNO as terminal oxidant

Zhi-Ming Wang, Xue-Ling Sang + Show 2 more

https://doi.org/10.1016/j.tetlet.2014.01.098

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Journal: Tetrahedron Letters	Publication Date: Jan 31, 2014
Citations: 10

Affiliation: Central China Normal University, State Key Laboratory of Synthetic Chemistry

#Cleavage Of CC Bond #Terminal Oxidant + Show 7 more

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Abstract

A new method for the conversion of internal alkenes into ketones without cleavage of CC bond by using dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin [RuIV(TDCPP)Cl2] as catalyst and 2,6-dichloropyridine N-oxide(Cl2pyNO) as oxidant is developed.

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